A number of cycloadducts between 2-acetyl- and 2-benzoyl-1,4-benzoquinones and dienes have been prepared and the direction of the subsequent acyl group migration has been shown to depend on the diene substituents. The initial adducts from 2-acetylnaphthoquinone and dienes either epimerised or yielded 9,10-anthraquinone on attempted rearrangement.
S. C. Cooper and P. G. Sammes, J. Chem. Soc., Perkin Trans. 1, 1984, 2407 DOI: 10.1039/P19840002407
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