The analytical solution for uptake curves of a single-component sorption under constant-volume/variable-pressure conditions has been derived, subject to certain simplifying assumptions. Rate mechanisms considered are intracrystalline diffusion and sorption-heat dissipation from the surface of the zeolite crystals to the surroundings.
M. Kočiřík, P. Struve and M. Bülow, J. Chem. Soc., Faraday Trans. 1, 1984, 80, 2167 DOI: 10.1039/F19848002167
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