Oxidative addition of Mel to [Rh(CO)2l2]– in aprotic solvents, the ‘rate-determining’ step in the carbonylation of methyl acetate and methyl halides(to acetic anhydride and acyl halides, respectively), is substantially promoted by iodide and bases (L, e.g. 1-methylimidazole).
C. E. Hickey and P. M. Maitlis, J. Chem. Soc., Chem. Commun., 1984, 1609 DOI: 10.1039/C39840001609
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