A new synthesis of the key intermediate (13) in the preparation of (+)-isocarbacyclin (1) is described, which involved the effective construction of bucyclo[3.3.0]octanone from a Corey lactone and regiocontrolled olefin formation from an allylic alcohol.
Y. Torisawa, H. Okabe and S. Ikegami, J. Chem. Soc., Chem. Commun., 1984, 1602 DOI: 10.1039/C39840001602
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