Issue 21, 1984

Phosphine complexes of main group elements: phosphinomethyl substituted aluminates as anionic phosphine ligands to lithium and X-ray structure of Me2Al(CH2PMe2)2Li(Me2NCH2CH2NMe2)

Abstract

Anionic aluminates or the type [MexAl(CH2PMe2)4 –x] were synthesized and shown to co-ordinate to a Li+ ion; according to an X-ray structure determination [Me2Al(CH2PMe2)2Li(Me2NCH2CH2NMe2)] contains a six-membered Al(C–P)2Li heterocycle.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1415-1416

Phosphine complexes of main group elements: phosphinomethyl substituted aluminates as anionic phosphine ligands to lithium and X-ray structure of Me2Al(CH2PMe2)2Li(Me2NCH2CH2NMe2)

H. H. Karsch, A. Appelt and G. Müller, J. Chem. Soc., Chem. Commun., 1984, 1415 DOI: 10.1039/C39840001415

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