Soluble conducting poly(acetylene)–poly(isoprene) block copolymers have been synthesized by using the polymeric catalyst formed by the reaction of poly(isoprenyl-lithium) with tetrabutoxytitanium in toluene at room temperature; an instantaneous polymerization of acetylene is observed leading to the formation of a block copolymer in which the poly(isoprene) chain length is the determining factors of the materials electrical behaviour.
M. Aldissi, J. Chem. Soc., Chem. Commun., 1984, 1347 DOI: 10.1039/C39840001347
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