The anionic triruthenium cluster [Ru3H(CO)11]–, anchored to silica via ammonium or pyridinium functional groups, exhibits a high catalytic activity for the water-gas shift reaction at low temperatures in the range 100–150 °C.
Y. Doi, A. Yokota, H. Miyake and K. Soga, J. Chem. Soc., Chem. Commun., 1984, 394 DOI: 10.1039/C39840000394
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