The alumina-supported anion cluster Al+[H3RuOs3(CO)12]– was formed by heating [H2RuOs3(CO)13] absorbed on γ-Al2O3 to 373–473 K under an H2+ CO atmosphere; the material is catalytically active for ethylene hydrogenation at 340 K and for but-1-ene isomerization at 330 K.
J. R. Budge, J. P. Scott and B. C. Gates, J. Chem. Soc., Chem. Commun., 1983, 342 DOI: 10.1039/C39830000342
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