Although the amphibole asbestos minerals all possess basically the same structural elements, symmetry transitions may occur depending on their cation distribution. In the absence of bulky cations, iron(II) ions tend to occupy the M4 sites in all three important varieties studied.
M. Luys, G. L. De Roy, F. Adams and E. F. Vansant, J. Chem. Soc., Faraday Trans. 1, 1983, 79, 1451 DOI: 10.1039/F19837901451
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