Successive treatment of olefins with PhSeCl and silver crotonate affords β-phenylselenocrotonates which, on reaction with triphenyltin hydride in the presence of azobisisobutyronitrile, are converted into γ-lactones by a process that introduces a new carbon–carbon bond.
D. L. J. Clive and P. L. Beaulieu, J. Chem. Soc., Chem. Commun., 1983, 307 DOI: 10.1039/C39830000307
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