The reaction of mesitylcopper(I), CuAr, with 1,2-bis (diphenylphosphino)ethane, dppe, gives [(dppe)2Cu2Ar2], whose molecular structure, determined by a single-crystal X-ray study, consist of a linear mononuclear [CuAr2]– unit with a tetrahedral [Cu(dppe)2]+ unit as counter-ion.
P. Leoni, M. Pesquali and C. A. Ghilardi, J. Chem. Soc., Chem. Commun., 1983, 240 DOI: 10.1039/C39830000240
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