Surface 1H n.m.r. spectroscopy provided details of the reaction of the SiO2-supported complex SlL–O–Rh(allyl)2 with H2 at 298 K, leading to propane, propene, and highly dispersed supported Rh metel, which was catalytically active for toluene hydrogenation.
S. J. DeCanio, H. C. Foley, C. Dybowski and B. C. Gates, J. Chem. Soc., Chem. Commun., 1982, 1372 DOI: 10.1039/C39820001372
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