Hydroxyl radicals formed by ionizing radiation in ice crystals are reversibly converted into ˙O– anions on cooling to ca. 4 K. Using D2O enriched in 17O, hyperfine coupling to 17O in ˙17OD and in ˙17O– radicals has been monitored. The results support the identification of these species, and shed light on their electronic structures.
M. C. R. Symons, J. Chem. Soc., Faraday Trans. 1, 1982, 78, 1953 DOI: 10.1039/F19827801953
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