Reaction of AgAsF6 with S8 in liquid sulphur dioxide leads to [Ag(S8)2]AsF6, which contains cyclo-octasulphur ligands; the X-ray structure shows that the silver atoms achive distorted four-co-ordination by 1,3-linkages to two S8 rings.
H. W. Roesky, M. Thomas, J. Schimkowiak, P. G. Jones, W. Pinkert and G. M. Sheldrick, J. Chem. Soc., Chem. Commun., 1982, 895 DOI: 10.1039/C39820000895
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