The use of zero-valent complexes and dehydroxylated alumina allows the synthesis of novel catalysts of supported Cr, Mo, and W which are ca. 1000-fold more active than traditional catalysts of these elements for alkene hydrogenation.
D. A. Hucul and A. Brenner, J. Chem. Soc., Chem. Commun., 1982, 830 DOI: 10.1039/C39820000830
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