The compound [7-(PMe2Ph){7-PtB16H18-9′-(PMe2Ph)]} is a complex of a macropolyhedral 16-vertex borane ligand based on the structure of an as yet unknown B6–B10conjuncto-borane; it is the first example of a contiguous 17-vertex cluster species, and has a number of other interesting features.
M. A. Beckett, J. E. Crook, N. N. Greenwood, J. D. Kennedy and W. S. McDonald, J. Chem. Soc., Chem. Commun., 1982, 552 DOI: 10.1039/C39820000552
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