Issue 6, 1982

Facile thermally-induced cluster oxidations in metallaborane chemistry: arachnonidocloso reaction sequences exhibited by iridanonaboranes and iridadecaboranes, and the stabilization of the iridium(V) oxidation state

Abstract

Iridanonaboranes and iridadecaboranes which have adjacent open-face bridging H atoms and terminal Ir–H atoms readily lose H2 in formal cluster oxidations which involve stable isolable iridium (V) species.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 346-348

Facile thermally-induced cluster oxidations in metallaborane chemistry: arachnonidocloso reaction sequences exhibited by iridanonaboranes and iridadecaboranes, and the stabilization of the iridium(V) oxidation state

J. Bould, J. E. Crook, N. N. Greenwood, J. D. Kennedy and W. S. McDonald, J. Chem. Soc., Chem. Commun., 1982, 346 DOI: 10.1039/C39820000346

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