Attempts to measure the kinetics of the unusual abstraction reaction, Me3Si.+ Me2SiCl2→ Me3SiCl + Me2SiCl using thermal radical sources were unsuccessful. Kinetic data were obtained by using a photochemical radical source, yielding unconventional Arrhenius parameters, the significance of which is discussed.
I. M. T. Davidson and J. I. Matthews, J. Chem. Soc., Faraday Trans. 1, 1981, 77, 2277 DOI: 10.1039/F19817702277
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