Arsenic pentafluoride interacts at low temperature with either butadiyne or nitric oxide to form the arsenic radical anion (·AsF5–); this radical anion generation and subsequent annihilation at higher temperatures governs the ‘overall’ half-reaction:3AsF5+ 2e–→ 2AsF6–+ :AsF3.
P. J. Russo, M. M. Labes and G. E. Kemmerer, J. Chem. Soc., Chem. Commun., 1981, 701 DOI: 10.1039/C39810000701
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