Carbonylation of Ti(η-C4H6)2(dmpe)[dmpe = 1,2-bis(dimethylphosphino)ethane] or reduction of TiCl4.2THF in the presence of dmpe and CO affords [Ti(CO)3(dmpe)3/2]n which reacts wih PF3 and dmpe to form Ti(CO)2(PF3)(dmpe)2, [a derivative of the non-existent Ti(CO)7], the X-ray crystal structure of which is reported.
S. S. Wreford, M. B. Fischer, J. Lee, E. J. James and S. C. Nyburg, J. Chem. Soc., Chem. Commun., 1981, 458 DOI: 10.1039/C39810000458
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