The reduction of phenylimidotrichlorobis-(trimethylphosphine)rhenium(V) in tetrahydrofuran by sodium amalgam under atmospheres of argon, nitrogen, hydrogen, carbon monoxide, and buta-1, 3-diene, leads to new complexes in all of which there is a phenylamido-group, Re(NHPh).
K. W. Chiu, W. Wong and G. Wilkinson, J. Chem. Soc., Chem. Commun., 1981, 451 DOI: 10.1039/C39810000451
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