Issue 7, 1981

Reactions of a triarylsulphonium salt with alkoxide nucleophiles: involvement of radical intermediates

Abstract

Tri-p-tolylsulphonium bromide reacts with sodium isopropoxide or potassium hydroxide to give toluene; solvent isotope labelling experiments clearly show involvement of the p-tolyl radical species rather than the corresponding anion in this reaction.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 346-347

Reactions of a triarylsulphonium salt with alkoxide nucleophiles: involvement of radical intermediates

S. Chung and K. Sasamoto, J. Chem. Soc., Chem. Commun., 1981, 346 DOI: 10.1039/C39810000346

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