Ethene and acetic acid react in the interlamellar regions of certain cation (e.g. Al3+)-exchanged montmorillonites to yield ethyl acetate as the sole product, and a variety of carboxylic acids readily add to C2–C8 alkenes at temperatures above 100 °C to yield the corresponding esters in high and selective yields.
J. A. Ballantine, M. Davies, H. Purnell, M. Rayanakorn, J. M. Thomas and K. J. Williams, J. Chem. Soc., Chem. Commun., 1981, 8 DOI: 10.1039/C39810000008
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