Ruthenium dioxide, which is known to be a catalyst for the oxidation of water to oxygen, has been observed to mediate hydrogen formation from water in a model system containing Ru(2,2′-bipyridyl)32+, methyl viologen, and ethylenediaminetetra-acetic acid with higher efficiency above pH = 5 than that previously observed with colloidal platinum as catalyst.
E. Amouyal, P. Keller and A. Moradpour, J. Chem. Soc., Chem. Commun., 1980, 1019 DOI: 10.1039/C39800001019
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