The ZnO- or CdS-catalysed photocycloreversion of the strained cage molecule (1) afforded the diene (2), which was also produced by a cerium ammonium nitrate-catalysed dark reaction and by photoexcitation of the charge-transfer complex of (1) with tetracyano-ethylene.
K. Okada, K. Hisamitsu and T. Mukai, J. Chem. Soc., Chem. Commun., 1980, 941 DOI: 10.1039/C39800000941
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