The esters of trans-9-hydroxy-10-phenylthio-or -10-chloro-9,10-dihydrophenanthrene are smoothly reduced under neutral conditions by tri-n-butylstannane to furnish, by radical elimination, phenanthrene and the nor-hydrocarbon formed from decomposition of the corresponding acyloxy radical.
D. H. R. Barton, H. A. Dowlatshahi, W. B. Motherwell and D. Villemin, J. Chem. Soc., Chem. Commun., 1980, 732 DOI: 10.1039/C39800000732
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