An X-ray crystal structure investigation of 12 cobalt(III) complexes has shown that the Co–NO2 bond length is shorter by an average of 0·05 Å when trans-to carboxylato-oxygen than when trans- to a nitrogen ligator.
R. Herak, N. Juranić and M. B. Ćelap, J. Chem. Soc., Chem. Commun., 1980, 660 DOI: 10.1039/C39800000660
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