A silyl-cuprate reagent adds regioselectively to terminal acetylenes and the intermediate (3) reacts with electrophiles to give 2,2-disubstituted vinylsilanes.
I. Fleming and F. Roessler, J. Chem. Soc., Chem. Commun., 1980, 276 DOI: 10.1039/C39800000276
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