Rapid reversible fission of a C–H bond in a metal complex: X-ray crystal structure of [RhHCl(But2PCH2CH2CHCH2CH2PBut2)]
Abstract
The occurrence and stereochemistry of a rapid reversible C–H fission in [[graphic omitted]But2)] is established by n.m.r. spectroscopy, including triple resonance INDOR, and by X-ray crystallography.