Issue 0, 1978

Luminescence spectrum of Cs2UO2Cl4

Abstract

The polarised luminescence spectrum of Cs2UO2CI4 has been measured at temperatures down to 10 K. Vibronic analysis shows that the lowest excited state of the UO2Cl2–4 ion has Eg(D4h) symmetry. Anharmonicity constants (x11 and x12) are derived for the U16O18OCl2–4 and U16O2Cl2–4 ions. The luminescence spectrum does not exactly mirror the previously reported absorption spectrum; reasons for this are discussed.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans. 2, 1978,74, 2210-2217

Luminescence spectrum of Cs2UO2Cl4

C. D. Flint and P. A. Tanner, J. Chem. Soc., Faraday Trans. 2, 1978, 74, 2210 DOI: 10.1039/F29787402210

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements