The classical trajectory technique has been used to analyse the thermoneutral oxygen atom exchange reaction at a microscopic level. The calculations show that a direct exchange mechanism makes the major contribution to the reactive cross section, and that very few reactions proceed via long-lived complexes. The calculated macroscopic rate constants at 300 and 500 K are in good agreement with the experimental results.
A. J. Stace and J. N. Murrell, J. Chem. Soc., Faraday Trans. 2, 1978, 74, 2182 DOI: 10.1039/F29787402182
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