The major product of u.v. photolysis of Me3SiN3 in Ar, N2, and CO matrices at 10 K is shown to be either Me2Si(H)N![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CH2 or Me2Si(H)CHNH; no evidence for π-bonded SiN species is obtained.
R. N. Perutz, J. Chem. Soc., Chem. Commun., 1978, 762 DOI: 10.1039/C39780000762
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