Bis(trimethylsilyl)bromamine, (Me3Si)2NBr, reacts with hydrocarbons to bring about bromination by a free radical chain mechanism in which the radical (Me3Si)2N· is responsible for hydrogen abstraction.
B. P. Roberts and C. Wilson, J. Chem. Soc., Chem. Commun., 1978, 752 DOI: 10.1039/C39780000752
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