The reaction of [Mn(H2O)2(O2CMe)3] with pyridine (py) produces the antiferromagnetic trinuclear complex [Mn3(py)3O(O2CMe)6], whose molecular structure, determined by X-ray methods, shows all three manganese atoms to be equivalent, with an average oxidation state of 2⅔.
A. R. E. Baikie, M. B. Hursthouse, D. B. New and P. Thornton, J. Chem. Soc., Chem. Commun., 1978, 62 DOI: 10.1039/C39780000062
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