Detailed spectra are described for acetyldiphenylphosphine oxide (1), prepared as a crystalline solid from acetyl chloride and methyl diphenylphosphinite. The oxide (1) is a potent acylating agent and readily undergoes carbonyl addition reactions. Acetoxydiphenylphosphine and (1) interconvert spontaneously, and then slowly form a dimer.
J. A. Miller and D. Stewart, J. Chem. Soc., Perkin Trans. 1, 1977, 1898 DOI: 10.1039/P19770001898
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