Issue 13, 1977

Evidence of ‘mixed-valency’ character in the X-ray photoelectron spectra of α-diantimony tetraoxide and barium bismuth trioxide

Abstract

X-Ray photoelectron spectra of the metal(III)–metal(V) oxides α-Sb2O4 and BaBiO3 are reported. Indications of ‘mixed-valency’ character in the metal core-electron spectra could be found only after careful pretreatment of the samples in situ. Under normal conditions both compounds appear to have surface phases containing just the lower oxidation state.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1977, 1238-1240

Evidence of ‘mixed-valency’ character in the X-ray photoelectron spectra of α-diantimony tetraoxide and barium bismuth trioxide

A. F. Orchard and G. Thornton, J. Chem. Soc., Dalton Trans., 1977, 1238 DOI: 10.1039/DT9770001238

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