The long-known cyanogenic glucoside acacipetalin, confirmed to be 2-(β-D-glucopyranosyloxy)-3-methylbut-2-enenitrile, can be produced from a natural β-D-glucopyranoside of 2-hydroxy-3-methylbut-3-enenitrile, which is distinguished from its epimer and named proacacipetalin.
M. G. Ettlinger, J. W. Jaroszewski, S. R. Jensen, B. J. Nielsen and F. Nartey, J. Chem. Soc., Chem. Commun., 1977, 952 DOI: 10.1039/C39770000952
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