Gibberellin A13 and A14 7-aldehydes have been tentatively identified as metabolites of gibberellin A12 aldehyde in a cell-free system derived from Gibberella fujikuroi; gibberellin A13 7-aldehyde is incorporated into gibberellic acid, and the C-20 carbon atom which is removed at this stage has been isolated as carbon dioxide.
B. Dockerill, R. Evans and J. R. Hanson, J. Chem. Soc., Chem. Commun., 1977, 919 DOI: 10.1039/C39770000919
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