Tris(triphenylphosphine)tetramethylenenickel(II) and biscyclopentadienyltetramethylenetitanium, prepared from the reaction of a 1,4-dilithiobutane and the transition metal dihalides react with olefins to produce substituted metallacyclopentanes; the stereochemistry and substitution pattern of the metallocycles formed from propene, octa-1,7-diene, and norbornadiene has been determined.
R. H. Grubbs and A. Miyashita, J. Chem. Soc., Chem. Commun., 1977, 864 DOI: 10.1039/C39770000864
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