Kinetic studies of the hydrolysis of chlorosilanes shows nucleophilic assistance by hexamethyl-phosphoric triamide, dimethyl sulphoxide, or dimethyl-formamide in nucleophilic substitution; the reaction is controlled by the entropy of activation, and takes place with retention of configuration at silicon instead of inversion as previous observed with acyclic chlorosilanes.
R. J. P. Corrju, G. Dabosi and M. Martineau, J. Chem. Soc., Chem. Commun., 1977, 649 DOI: 10.1039/C39770000649
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...