Treatment of PCl3 with o-HOC6H4COCH2R (R = H or Et) and NEt3 affords 2-chloro-1,3,2-dioxaphosphorinans, which can be readily converted into the corresponding 2-alkoxy derivatives; evidence is presented for the formation of analogous derivatives on similar reaction of acetylacetone and PCl3.
G. M. L. Cragg, B. Davidowitz, R. G. F. Giles and R. J. Haines, J. Chem. Soc., Chem. Commun., 1977, 569 DOI: 10.1039/C39770000569
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...