2 H N.m.r. spectroscopy has been employed to establish that in fenugreek seedlings, (6aR, 11aR)-demethylhomopterocarpin is synthesised from 2′,7-dihydroxy-4′-methoxyisoflavone via an overall trans addition of hydrogen to the double bond.
P. M. Dewick and D. Ward, J. Chem. Soc., Chem. Commun., 1977, 338 DOI: 10.1039/C39770000338
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