Diethyl azodicarboxylate reacts with imines of α-amino-acid esters, probably by way of an ene-reaction, to give either imines of the corresponding dehydroamino-acid ester or triazolidines, depending on the structure of the α-amino-acid ester.
R. Grigg and J. Kemp, J. Chem. Soc., Chem. Commun., 1977, 125 DOI: 10.1039/C39770000125
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