Issue 1, 1977

pH-Induced co-ordination geometry change in a macrocyclic nickel(II) complex

Abstract

The co-ordination geometry of the NiII complex with the new macrocyclic ligand L, which contains a side chain, is controlled by the pH of the solution, the square-planar yellow diamagnetic form and the octahedral blue paramagnetic one being stable below and above pH 6·3, respectively.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 15-16

pH-Induced co-ordination geometry change in a macrocyclic nickel(II) complex

T. J. Lotz and T. A. Kaden, J. Chem. Soc., Chem. Commun., 1977, 15 DOI: 10.1039/C39770000015

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