Perfluoroalkyl iodides react with carbon dioxide and sulphur dioxide, in the presence of zinc–copper type metallic couples in dimethyl sulphoxide, to give the corresponding carboxylic and sulphonic acids derivatives in 40–80% yields.
H. Blancou, P. Moreau and A. Commeyras, J. Chem. Soc., Chem. Commun., 1976, 885 DOI: 10.1039/C39760000885
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