The addition of chloronitrile oxide to the nitronate salts of αβ-unsaturated-α-nitrocrotonic esters yields the 3-chloroisoxazoline adducts, in an efficient reaction; further transformations convert these into the free aminoderivatives which are members of a class of biologically interesting amino-acids.
J. E. Baldwin, C. Hoskins and L. Kruse, J. Chem. Soc., Chem. Commun., 1976, 795 DOI: 10.1039/C39760000795
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