The reaction between oximes and tervalent phosphorus compounds to give the corresponding alkylidenamide [R12P(O)N![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CR2R3] proceeds through the PIII isomer (R12PO–NCR2R3) which spontaneously rearranges (at least in part) by a radical-cage mechanism.
C. Brown, R. F. Hudson, A. Maron and K. A. F. Record, J. Chem. Soc., Chem. Commun., 1976, 663 DOI: 10.1039/C39760000663
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