Using a solution calorimetric method the standard enthalpies of formation at 298·15 K of PBr5(c), BPCl8(c), and BPBr8(c) have been determined as –60·5 ± 0·6, –223·95± 0·6, and –135·5 ± 0·7 kcal mol–1, respectively, the first two results differing significantly from literature sources.
A. Finch, P. J. Gardner, P. N. Gates, A. Hameed, C. P. McDermott, K. K. SenGupta and M. Stephens, J. Chem. Soc., Dalton Trans., 1975, 967 DOI: 10.1039/DT9750000967
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