Issue 21, 1975

Iridium and rhodium dihydride–hydroborate complexes of the type [MH2(BH4)L2]

Abstract

Complexes of the type [IrH2(BH4)L2] are described (L = bulky tertiary phosphine) and are the first examples of metal–hydroborate complexes in which the BH4 ligand is not fluxional; an analogous rhodium complex shows some fluxionality.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 861-862

Iridium and rhodium dihydride–hydroborate complexes of the type [MH2(BH4)L2]

H. D. Empsall, E. Mentzer and B. L. Shaw, J. Chem. Soc., Chem. Commun., 1975, 861 DOI: 10.1039/C39750000861

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