Iridium and rhodium dihydride–hydroborate complexes of the type [MH2(BH4)L2]
Abstract
Complexes of the type [IrH2(BH4)L2] are described (L = bulky tertiary phosphine) and are the first examples of metal–hydroborate complexes in which the BH4 ligand is not fluxional; an analogous rhodium complex shows some fluxionality.