The luminescent state of bilirubin in EPAF glass at 77 K is very short lived (<5 ns) and is therefore regarded as the singlet; there is evidence that this emission occurs from a species of bilirubin distinct from that predominating in solution at room temperature.
R. Bonnett, J. Dalton and D. E. Hamilton, J. Chem. Soc., Chem. Commun., 1975, 639 DOI: 10.1039/C39750000639
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